Absolute absorption spectroscopy based on molecule interferometry

Author(s): S. Nimmrichter, K. Hornberger, H. Ulbricht, M. Arndt

Journal: Phys. Rev. A

Volume: 78

Page(s): 063607

Year: 2008

DOI Number: 10.1103/PhysRevA.78.063607

Link: Link to publication


We propose a method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photoinduced fragmentation or ionization. The method is based on resolving the recoil resulting from photon

absorption by means of near-field matter-wave interference, and it thus applies even to very dilute beams with low optical densities. Our discussion includes the possibility of internal state conversion as well as fluorescence. We assess the influence of various experimental uncertainties and show that the measurement of absolute absorption cross sections is conceivable with high precision and using existing technologies.

Note: http://arxiv.org/abs/0811.1141

File: Link to PDF

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